It is nice to know that you are able to control your DAQ card using Mathematica!
I worked on this long time ago and unfortunately I do not remember many things about this project now. I tried to find some resources for you.
task@AIChannels@CreateVoltageChannel[
"cDAQ1Mod3/ai1, cDAQ1Mod3/ai2",
"",
termConfig,
-6.0, (*voltage level*)
6.0,
aiVolts
]
should work for multi-channel measurements. I also found this document Using NI-DAQmx in Text Based Programming Environments was helpful. It may help you as well.