I'm not sure exactly what kind of output you would like to get here. The rational numbers are dense in the reals, so you would be plotting your function for 14/10 and 15/10, but then also for the midpoint 29/20, and the midpoint between that and the boundaries, and the midpoints between midpoints. Even so, that would only give a subset of the rationals equivalent to the set of binary fractions.
I guess you could use ListPlot, with the argument of ListPlot being some set of rational numbers, maybe even ordering them by where they appear in the famous snake-like path through the rationals
1/1 2/1 3/1
1/2 2/2 3/2
1/3 2/3 3/3
Then the code would be
ListPlot[ Table[{x,Exp[x]}, {x, {1,2,1/2,1/3,2/3,3/2,3}}] ]
Do you have a more detailed description of what you have in mind? Maybe with an example?