Hi Zhenyu
The Problem here is that the headerline in the xlsx file contains duplicate names.
HCO3-, CO2, CO32- appear two times.
Also the header for column A and B are identical (empty).
Eliminate the duplicates and it will work as expected.
Alternatively you can exactly specify the sheets/columns/rows to import:
(Sheet 1, All rows, columns 3;;7
Import["2.xlsx", {"Dataset", 1, All, 3 ;; 7}, "HeaderLines" -> 1]
Robert