Hi Hongyi
The circle numbered 1 is not a URL, it is a button in an HTML form (you can see this by using Chrome Developer Tools). You can submit the form for the last form input element which is "ITA Settings" like this
session = StartWebSession[];
page = WebExecute[
"OpenPage" ->
"https://www.cryst.ehu.es/cgi-bin/cryst/programs/nph-getgen?list=new&what=gen&gnum=7"]
inputs = WebExecute[session, "LocateElements" -> "Tag" -> "Input"]
WebExecute[session, "ClickElement" -> Last@inputs]
That will take you to the page with the circle number 2. On that page, each row of the table (apart from the header) does have a link. To navigate to a particular one
anchors = WebExecute["LocateElements" -> "Tag" -> "a"]
pb11 = anchors //
Select[StringStartsQ[WebExecute[session, "ElementText" -> #], "P b 1 1"] &]
WebExecute[session, "ClickElement" -> pb11]