You seem to intend that
$q$ depends on
$\theta2$ only. That is not the case
In[74]:= Variables[q]
Out[74]= {\[Omega]3, \[Omega]4, Cos[0.0174533 \[Theta]2],
Cos[0.0174533 \[Theta]3], Cos[0.0174533 \[Theta]4],
Csc[0.0174533 \[Theta]3], Csc[0.0174533 \[Theta]4],
Sec[0.0174533 \[Theta]3], Sec[0.0174533 \[Theta]4],
Sin[0.0174533 \[Theta]2], Sin[0.0174533 \[Theta]3],
Sin[0.0174533 \[Theta]4]}
and therefore the
Plot[q, {\[Theta]2, 0, 2 Pi}]
remains empty. You need to replace
$\theta3$ and
$\theta4$ by the results of the previous substitution.
What is the purpose of this calculation? To eliminate
$\theta3, \theta4, \omega3, \omega4, \alpha3, \alpha4$ from the equations in order to get one expression in
$\theta2$?