I am not sure what you are trying to do with your code, it does not seem to work. Perhaps:
MemberQ[RealDigits[N[Pi, 10]][[1]], 0]
False
MemberQ[RealDigits[N[Pi, 50]][[1]], 0]
True
or maybe to see where 0s are:
Position[RealDigits[N[Pi, 100]][[1]], 0]
{{33}, {51}, {55}, {66}, {72}, {78}, {86}, {98}}