Guten Tag Michael.
Try  (you can transfer the following line to a notebook via copy and paste)
Plot[Tan[x] - x, {x, 0, 15}]
From the plot you can see that the zeros are in the vicinity of startvalues (given below. You may well use other startvalues).
Then apply Findroot to each of them to get the zeros  (here FindRoot is incorporated in a Function which is applied to the list of startvalues).
In[19]:= startvalues = {4, 7, 10.5, 14};
FindRoot[Tan[x] - x == 0, {x, #}, WorkingPrecision -> 20] & /@ startvalues
Out[20]= {{x -> 4.4934094579090641753}, {x -> 7.7252518369377071642},
{x -> 10.904121659428899827}, {x -> 14.066193912831473480}}
For example
In[22]:= Tan[10.9041216594288] - 10.9041216594288
Out[22]= -1.19265*10^-11
From a Plot like
Plot[Tan[x] - x, {x, 15, 35}, Epilog -> {PointSize[.02], Red, Point /@ Table[{(2 j - 1) Pi/2, 0}, {j, 20}]}]
one may conclude that the zeros of Tan[x]-x approach (2 n - 1)  Pi / 2.
I hope this helps.