The fluid library automatically accesses the fluids defined inside the Modelica->Media library.
If all the thermodynamic relations are known then a custom fluid can be created. Some documentation can be found here:
https://reference.wolfram.com/system-modeler/libraries/Modelica/Modelica.Media.UsersGuide.MediumDefinition.html
You can of course get in touch with Wolfram Technical Consulting if you want us to add custom fluids for you.
Unfortunately, as the ExternalMedia library is dependent on new features that we are working on, we do not have a target date for it yet.