I figured it out. If the column vector has an ArrayDepth of 1 like {9,5,2}, the following will work.
MapThread[Append, {coefficientMatrix, {9, 5, 2}}] // MatrixForm
If the column vector has an ArrayDepth of 2 like {{9},{5},{2}} then this will work:
MapThread[
Append, {coefficientMatrix, Flatten[{{9}, {5}, {2}}]}] // MatrixForm
To get a coefficient matrix,
coefficientMatrix = {{1, 0, 5}, {-2, 2, 0}, {1, -8, -5}}
Map[Most][
MapThread[Append, {coefficientMatrix, {9, 5, 2}}]] // MatrixForm
and the column vector:
Map[Last][
MapThread[Append, {coefficientMatrix, {9, 5, 2}}]] // MatrixForm
Another option is to use the Resource Functions AugmentedMatrix and CoefficientMatrix created by Dennis M Schneider.