I don't understand how isotopes abundances are determined or how the uncertainties in the measures are modeled probabilistically, But the following comes very close to reproducing the intervals for the isotopes found at https://www.ciaaw.org/lithium.htm:
IsotopeData["Lithium6", "IsotopeAbundance"]/100 // QuantityMagnitude //
N@# + 10^-Accuracy[#] 1.73 {-1, 1} &
(* {0.018917, 0.078083} -- cf. [0.019, 0.078] (CIAAW) *)
IsotopeData["Lithium7", "IsotopeAbundance"]/100 // QuantityMagnitude //
N@# + 10^-Accuracy[#] 1.73 {-1, 1} &
(* {0.921917, 0.981083} -- cf. [0.922, 0.981] (CIAAW) *)
I cannot explain the 1.73
scaling factor. It is close, but not very close, to the
$z$-score of 1.645
, used in say, constructing a 95%-confidence interval. It's closer to
$\sqrt{3}$, which means nothing to me.
My understanding extends no farther than the intervals are rather close to the CIAAW intervals, and that the precision in the arbitrary-precision quantities most likely encodes the uncertainty of the value in some form.