Mitchell,
in your code you have too many curly brackets; try
Graphics[{Red, Arrow[{{0, 0}, 3 {1, 3}}], Blue, Arrow[{{0, 0}, 2 {2, 5}}]}, Axes -> True, AxesLabel -> {"x", "y"}]
For an understanding of eigenvectors here is a simple example to play with: Red are the eigenvectors, green represents the input vector and blue the resulting output. The vectors of the vector field gives the direction of this output.
mat = {{1., -.5}, {-1, -.5}};
{ev, evec} = Eigensystem[mat];
Manipulate[
VectorPlot[mat . {x, y}, {x, -3, 3}, {y, -3, 3},
Epilog -> {Red, Arrow[ev[[1]] {{0, 0}, evec[[1]]}],
Arrow[ev[[2]] {{0, 0}, evec[[2]]}],
Arrow[-ev[[1]] {{0, 0}, evec[[1]]}],
Arrow[-ev[[2]] {{0, 0}, evec[[2]]}], Green, Arrow[{{0, 0}, vec}],
Blue, Arrow[{{0, 0}, mat . vec}]},
PerformanceGoal -> "Quality"], {{vec, {1, 1}}, Locator}]
Does that help? Regards -- Henrik