In general I think you will have to break up the region into convex regions. I don't know if there is a routine that will triangulate it. Maybe if you gave a practical but more generic case?
However, in the case you present it is quite simple.
vertexPoints = {{-6.17, -33.75}, {-9.35, -33.75}, {-9.35, -33.78}, {-9.35, -39.375}, {-9.35, -45.435}, {-9.35, -45.45}, {-9.22, -45.45}, {-9.22, -39.375}, {-6.17, -39.375}, {-6.17, -33.78}, {-6.17, -33.75}};
which plots as:
Graphics[
{Line[vertexPoints],
AbsolutePointSize[5], Point /@ vertexPoints},
AspectRatio -> 1,
PlotRange -> {{-10, -5}, {-50, -30}},
Frame -> True,
ImageSize -> 300]

The Boole function for the electrode region is given by:
inElectrode[x_,
y_] := (-9.35 <= x <= -6.17) \[And] (-39.735 <=
y <= -33.78) \[Or] (-9.35 <= x <= -9.22) \[And] (-45.45 <=
y <= -39.735)
which plots as:
RegionPlot[inElectrode[x, y], {x, -10, -5}, {y, -50, -30},
PlotPoints -> 30]
