Your function Model9, does not evaluate to a solution of the differential equation. E.g.,

Model9[.03, .046, .0666, .05, .1]

returns

Cb[0.1] /. {Derivative[1][Cc][t] == 
   137.344 (0.0378 Cam[t] + 0.0662 Cb[t] + 0.0378 Cbm[t] - 
      0.0028975 Cc[t]), 
  Derivative[1][Ca][t] == 20000. (-0.0229 Ca[t] + 0.0378 Cam[t]), 
  Derivative[1][Cb][t] == 
   925.926 (0.02 - 0.1091 Cb[t] + 0.0378 Cbm[t]), 
  Derivative[1][Cam][t] == 
   2472.19 (0.0229 Ca[t] - 0.0756 Cam[t] + 0.001145 Cc[t]), 
  Derivative[1][Cbm][t] == 
   2472.19 (0.0229 Cb[t] - 0.0756 Cbm[t] + 0.001145 Cc[t]), 
  Cam[0] == 0, Cbm[0] == 0, Cc[0] == 0, Cb[0] == Cb0, Ca[0] == 0}

Without working though your Model9 in detail I cannot say what's going on here. I would recommend debugging your Model9 so that it executes properly before trying it out in the NonlinearModelFit

HI, I tried fixing that. But still I am getting an error. I have attached a changed file for reference. Please help me to solve the error

Thanks,

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