You left the function Cs out of the dependent variable list. You also gave
Nh[t] == 1, No[t] == 1, Ni[t] == 1
as algebraic equations. Perhaps you meant it to be
Nh[0] == 1, No[0] == 1, Ni[0] == 1?
You should also give an initial value for Cs. The following works:
NDSolve[{Cp'[t] == Gp - Mp,
Ch'[t] == Mp + Ms + Mm - Dsh,
Co'[t] == Mp + Ms + Mm - Dmo - Dso,
Cs'[t] == es Us - Ms,
Cm'[t] == em Um - Mm,
Np'[t] == Upn - rp Mp + \[Phi]m,
Nh'[t] == fhp rp Mp + fhs rs Ms + fhm rm Mm - rh Dsh,
No'[t] == fop rp Mp + fos rs Ms + fom rm Mm - ro (Dmo + Dso),
Ni'[t] == Datm - L - Umn + \[Phi]s,
Cp[0] == 1, Ch[0] == 1, Co[0] == 1, Cm[0] == 1, Np[0] == 1,
Nh[0] == 1, No[0] == 1, Ni[0] == 1, Cs[0] == 0}, {Cp, Ch, Co, Cm,
Np, Nh, No, Ni, Cs}, {t, 0, 100}]