This will produce the solution. It of course includes 3 integration constants, C[1],C[2], C[3].
eqs = {r1'[t], r2'[t],
r3'[t]} == {{-k13, k21, 0}, {0, -k21, k32}, {k13, 0, -k32}}.{r1[
t], r2[t], r3[t]};
sol = DSolve[eqs, {r1, r2, r3}, t] // First;
These could also be solved for by including them in the equation set.
sol2 = DSolve[{eqs, {r1[0] == 1, r2[0] == 1, r3[0] == 1}}, {r1, r2,
r3}, t] // First;