Does this do what you want?  (I've reduced the number of iterations to 10 to minimize the output.)
jac[A_, b_, xstart_] := Module[{n, k, i, j, xneu, xalt},
   n = Length[b];
   xalt = xstart;
   k = 0;
   While[k < 10,
    xneu = b;
    For[i = 1, i <= n, i++,
     For[j = 1, j <= n, j++, 
      If[i != j, xneu[[i]] = xneu[[i]] - A[[i, j]]*xalt[[j]]]];
      xneu[[i]] = xneu[[i]]/A[[i, i]]]; 
    xalt = xneu;
    k++]; 
   xalt];
A = {{10, 14, 11}, {13, -66, 14}, {11, -13, 12}};
b = {1, 1, 1};
xstart = {0, 0, 0};
jac[A, b, xstart]
(* {1382598113217283/36067178188800000, 
  379022657204357/22132132070400000, 
  -(4712310469911859/486906905548800000)} *)