Anderson,
You can do that programmatically with the SetOptions command. First you need a handle to your Notebook. You can specify it multiple ways (see Guide to Notebook programming. Lets get all of the notebooks and pick one.
mybooks = Notebooks[]
slideshow = mybooks[[3]]
Now look at the options:
In[72]:= Options[slideshow]
Out[72]= {
ScreenStyleEnvironment -> "Working",
StyleDefinitions -> "Default.nb",
WindowMargins -> {{42, Automatic}, {Automatic, 24}},
WindowSize -> {808, 751}}
Now change the show environment:
SetOptions[slideshow], ScreenStyleEnvironment -> "Working"]
or
SetOptions[slideshow], ScreenStyleEnvironment -> "SlideShow"]
Using this you can make a program to automatically process your slide shows.
Regards,
Neil