I have /usr/local/bin/brew.
Don't know how to check if this executable is x86 or arm.
I don't have the symlinks in /usr/local/lib pointing to ffmpeg in Cellar.
But I do have ffmpeg in /usr/local/Cellar.
The /usr/local/opt/ffmpeg is a symlink to the version in /usr/local/Cellar.
So in short : it looks like /usr/local/lib was not used but instead it is /usr/local/opt/ffmpeg.
I do see some codecs in /usr/local/lib like libvorbisenc.a
But the libavcodec.58 libavformat.58 libavutil.56 libavfilter.7 libswscale.5 libswresample.3 are in the ffmpeg folder.