Of the following lines, only the first one gives what I was expecting:
Style[TraditionalForm[a + b <= 1],
FontFamily -> "Latin Modern Roman"]
Style[TraditionalForm[a + b <= 1], FontFamily -> "Latin Modern Math"]
Style[TraditionalForm[a + b <= 1], FontFamily -> "Computer Modern"]
Style[TraditionalForm[a + b <= 1], FontFamily -> "LaTeX"]
Style[a + b <= 1, FontFamily -> "LaTeX"]
The purpose was to imitate the standard TeX look.